Solid state organic amine detection in a photochromic porous metal organic framework.

Solid state organic amine detection in a photochromic porous metal organic framework† †Electronic supplementary information (ESI) available: Experimental procedures and additional supporting data. CCDC 1024270 and 1024271. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc03224a Click here for additional data file. Click here for additional data file.

Synthesis of Different Copper Oxide Nano-Structures From Direct Thermal Decomposition of Porous Copper(ΙΙ) Metal-Organic Framework Precursors

Copper oxide nanostructures have been successfully synthesized via one-step solid-state thermolysis of two metal-organic frameworks, [Cu3(btc)2] (1) and [Cu(tpa).(dmf)] (2), (btc = benzene-1,3,5-tricarboxylate, tpa = therephtalic acid = 1,4-benzendicarboxylic acid and dmf = dimethyl formamide) under air atmosphere at 400,  500, and 600°C. It has also been found that the reaction temperature pla...

Synthesis and Characterization of Nano-Structure Copper Oxide From Two Different Copper (II) Metal-Organic Framework Precursors

Nano-structured copper oxides were successfully prepared through direct calcination of 1D ladderlike metal-organic framework [Cu2(btec)(2,2'-bipy)2]∞, (btec = 1,2,4,5-benzenetetracarboxylate and 2,2'-bipy = 2,2'-bipyridine) and porous coordination polymer [Cu(BDC)(bipy)](BDCH2), (BDC = 1,4-benzenedicarboxylate; bipy = 4,4'-bipyridine). The nano-structure of the as-synthesized samples are charac...

In this paper, the effect of nanocatalytic metal-organic framework based on copper metal and bis-tetrazolamine (CuBTA) ligand functionalized with cobalt (II) oxide nanoparticles on the thermal decomposition behavior of ammonium perchlorate (AP), using differential survey calorimetry (DSC) has been reviewed. First, the metal-organic framework (CuBTA) was synthesized from the raw materials of cop...

Macrocyclic and Supramolecular Chemistry: How Izatt–Christensen Award Winners

Edited by Reed M. Izatt. © 2016 John Wiley & Sons, Ltd. Published 2016 by John Wiley & Sons, Ltd. Inorganic zeolites [1], mesoporous silica [2], and porous carbon [3] are useful materials because of their permanent porosity imparted by their architectural stability in the absence of guest molecules. The chemical functionalization and structure control of these classes of porous materials have b...